Boron nitride nanotubes: Pronounced resistance to oxidation
نویسندگان
چکیده
Boron nitride ~BN! nanotubes have the same nanostructure as carbon nanotubes but are found to exhibit significant resistance to oxidation at high temperatures. Our systematic study has revealed that BN nanotubes are stable at 700 °C in air and that some thin nanotubes ~diameter less than 20 nm! with perfect multiwalled cylindrical structure can survive up to 900 °C. Thermogravimetric analysis reveals an onset temperature for oxidation of BN nanotubes of 800 °C compared with only 400 °C for carbon nanotubes under the same conditions. This more pronounced resistance of BN nanotubes to oxidation is inherited from the hexagonal BN and also depends on the nanocrystalline structure. This high level of resistance to oxidation allows promising BN nanotube applications at high temperatures. © 2004 American Institute of Physics. @DOI: 10.1063/1.1667278#
منابع مشابه
Synthesis of boron nitride nanotubes and their applications
Boron nitride nanotubes (BNNTs) have been increasingly investigated for use in a wide range of applications due to their unique physicochemical properties including high hydrophobicity, heat and electrical insulation, resistance to oxidation, and hydrogen storage capacity. They are also valued for their possible medical and biomedical applications including drug delivery, use in biomaterials, a...
متن کاملUtilization of multiwalled boron nitride nanotubes for the reinforcement of lightweight aluminum ribbons
Multiwalled boron nitride nanotubes (BNNTs) have very attractive mechanical and thermal properties, e.g., elasticity, tensile strength, and high resistance to oxidation, and may be considered as ideal reinforcing agents in lightweight metal matrix composites. Herein, for the first time, Al-BNNT ribbons with various BNNT contents (up to 3 wt.%) were fabricated via melt spinning in an argon atmos...
متن کاملPurification of Yard-Glass Shaped Boron Nitride Nanotubes
An efficient method for purification of Yard-Glass Shaped Boron Nitride NanoTubes (YG-BNNTs) fabricated via a Chemical Vapour Reaction (CVR) route has been developed. Impurities including carbon, Boron Nitride (BN), and Fe species in the pristine YG-BNNT sample are removed by a combined physical and chemical procedure which involv<e...
متن کاملSuperhydrophobicity of boron nitride nanotubes grown on silicon substrates.
Partially vertical aligned boron nitride nanotubes (BNNTs) on Si substrates are found to be superhydrophobic in contrast to boron nitride (BN) thin films. While the hexagonal-phase BN films are partially wetted by water with advancing contact angle of about 50 degrees , partially vertically aligned BNNTs can achieve superhydrophobic state with advancing water contact angle exceeding 150 degrees...
متن کاملTheoretical comparison of thermodynamic parameters, NMR analysis, electronic properties of Boron Nitride and Aluminum Nitride nanotubes
In this research, geometrical structures of armchair single walled boron nitride nanotube (SWBNNT) and armchair single walled aluminum nitride nanotube (SWAlNNT) were optimized by Density Functional Theory (DFT) in the gas phase, both having the same length of 5 angstrom and n=9, m=9. B3LYP/6-31G* level of theory have been used to determine and compare electronic properties, n...
متن کامل